重读 phase transformation diagram (图)

本帖于 2010-04-17 19:47:56 时间, 由版主 林贝卡 编辑


首先声明: 纯属闲得无聊,独乐乐不如众乐乐。 BEAR & BILLINMON 别砸我 这两天没事在家炼长生不老的丹药. 时代不同了,现在是科技炼丹,还得看相图。 很久以前学过两天相变&相图。今天重读,理解却不一样了。看来学业是荒废了。 just found out that the two-phase phase transformation is similar to relationship 看图说话 EFFORT: the effort/energy either side put to keep the relation Emin: minimum effort required to win the love of the opposite side if both side put equal effort and likes each other. (追到手,开始”热“恋) Em: minimum effort required for male to move the female and eventually win the love of the female. phase transforms from 单恋 to LOVE Ef: minimum effort required for female to move the male and eventually win the love of the male. phase transforms from 单恋 to LOVE KEY POINTS - in general Em/Ef is much higher than Emin which means that love needs contributions from both sides. - make sure to find the critical point SF_optimal (彼此的感觉 level) so that less effort is required to be in (mutual) love. normlly SF is less than or equal to 0.5 (接近对称的感情) - Em (Ef as well) in general is close to infinite. (单相思是徒劳的) Case studies (let's take a few typical examples in 美女坛) CASE1 - M=熊大师;; F=Eagle - EFFORT: 情诗 - at the begging, it's more look like a uni-directal love (SF is aound SF1). those love sonnets (&儿歌) are too hot for Eagle & Eagle is touched/moved (SF move towards to SF_optimal) - END-phase: LOVE - what we learn from Bear's case: - more effort at the bigging might change the love course to be more favorable - be talented & smart CASE2 - M=Billinmon/不学王明; F=Lilac09/小千 - EFFORT: ZT - SF=0. Lilac09/小千were happy while they don't want Billinmon know - End-phase: still 单相思 - lesson for Billinmon: read the love phase diagram more; post some E-文 readings so that your idols know little bit more about you (we all know & agree U R niu-ren); better not use extremely approach such as "有贤惠,善良女子爱我不?"; learn from 熊大师 & change your approach which is too WILD (may be ok if you are 靖哥哥 & your 蓉儿 likes it) -------------------------------------------------------------------------- ZT (as reference,technical illustration of the eutectic phase diagram) Eutectic diagram with partial solubility of the components in solid state This kind of phase diagram is a “hybrid” of the diagram with complete solid and liquid solution and the eutectic diagram (the metals are completely soluble in liquid state and entirely insoluble in solid state). Consider solidification of an alloy with concentration C. When the alloy temperature is higher than TL, single liquid phase exists (point M on the diagram). When the temperature reaches the value TL (point M1 on the liquidus curve) solidification starts. According to solidus curve the first solid crystals (primary crystals) of the α-phase have composition C1. Further cooling of the alloy causes changing of the liquid phase composition according to the liquidus curve and when the alloy temperature reaches a certain intermediate value T (position MT ), liquid phase of composition Cy and solid α-phase of composition Cx are in equilibrium. At the temperature equal to TE (eutectic temperature) formation of the primary crystals stops and the remainding liquid phase , having composition CE (eutectic composition), transforms to a finely devided mixture of small solid crystals of α-phase and β-phase (eutectic phase transformation). At this temperature all α-phase crystals have composition Cα and all crystals of β-phase have composition Cβ. Relative amounts of the α-phase primary crystals and the eutectic mixture may be calculated by the “lever rule” : WP / WE = M2E / M2N or WP / WE = (CE-C) / (C- Cα) Where: WP – weight of the α-phase primary crystals; WE – weight of the eutectic mixture; Just below the eutectic temperature TE the alloy consists of two solid phase: α-phase and β-phase, relative amounts of whichis determined by the “lever rule” : Wα / Wβ = M2F / M2N or Wα / Wβ = (Cβ-C) / (C- Cα) Where: Wα – weight of the α-phase; Wβ – weight of theβ-phase; During further cooling solid solution phases (α-phase and β-phase) change their compositions according to the solvus curves NN3 and FF3 . Solvus curve determins formation of solid solution phase from another solid solution phase – similar to liquidus curve. At the temperature T3 α-phase crystals have composition Cα and all crystals of β-phase have composition Cβ. Hypo-eutectic alloys If an alloy composition C is lower, than eutectic composition CE , solidification of the alloy starts from formation of the primary crystals of α-phase according to the left branch of the liquidus curve. These alloys are called hypo-eutectic. Hyper-eutectic alloys If an alloy composition C is higher, than eutectic composition CE , solidification of the alloy starts from formation of the primary crystals of β-phase according to the right branch of the liquidus curve. These alloys are called hyper-eutectic. Eutectoid phase transformation is analogous to the eutectic transformation, however it occurs with a solid solution phase, breaking up into a mixture of two finely divided phases of different compositions.

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既有专业图表,又有看图说话,还有CASEs呢, 真丰富。 -婉蕠- 给 婉蕠 发送悄悄话 婉蕠 的博客首页 (126 bytes) () 04/17/2010 postreply 12:39:36

最后理论部分需专业人员解读;两个例子明了易懂,因为我们陪着走过来的。 -billnet- 给 billnet 发送悄悄话 billnet 的博客首页 (0 bytes) () 04/17/2010 postreply 12:45:16

123学问不是一般的大呀。可以提交作博士论文了:) -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (0 bytes) () 04/17/2010 postreply 13:00:06

oops,忘了123您小学还没毕业呢。。haha -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (0 bytes) () 04/17/2010 postreply 13:29:06

hahahaha,太好玩了这个,esp. the lesson part. -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (0 bytes) () 04/17/2010 postreply 13:04:42

密码呀,我当时招你为徒也不是乱招的 -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (36 bytes) () 04/17/2010 postreply 21:04:59

你这么厉害,给听听上面那首e歌好不好,是要表达什么? -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (0 bytes) () 04/17/2010 postreply 21:09:13

sweetie, i am so sorry -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (34 bytes) () 04/17/2010 postreply 21:19:12

here -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (865 bytes) () 04/17/2010 postreply 21:26:01

噢,老熊肯定在正在洗盘子。。。 -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (0 bytes) () 04/17/2010 postreply 21:56:40

sounds like ancient wisdom -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (102 bytes) () 04/17/2010 postreply 22:14:11

hmm。按照你的说法,回去又看了lyrics, -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (96 bytes) () 04/17/2010 postreply 22:25:03

sweetie I agree -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (123 bytes) () 04/17/2010 postreply 22:42:04

嗯,这种理解很理性。 -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (51 bytes) () 04/18/2010 postreply 09:02:55

sweetie -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (37 bytes) () 04/17/2010 postreply 23:07:15

I see your point -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (146 bytes) () 04/17/2010 postreply 23:13:09

this one is very simliar to what i thought yesterday, which -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (23 bytes) () 04/18/2010 postreply 09:12:39

this is what i thought: -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (502 bytes) () 04/18/2010 postreply 09:38:49

sweetie that's the best interpretation. I love it, yes I do. -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (53 bytes) () 04/18/2010 postreply 10:43:59

another division -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (37 bytes) () 04/17/2010 postreply 23:14:55

haha, i know, you never forget this case... -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (0 bytes) () 04/18/2010 postreply 09:08:46

ancient wisdom: divide and conquer -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (89 bytes) () 04/18/2010 postreply 00:13:26

furthermore we should be more ready -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (26 bytes) () 04/18/2010 postreply 00:15:20

you are brilliant, bear. -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (294 bytes) () 04/18/2010 postreply 08:55:11

oops,should be 'from YOUR own exp.." -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (0 bytes) () 04/18/2010 postreply 09:15:07

I have become smarter since you came into my life -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (16 bytes) () 04/18/2010 postreply 10:46:45

密码呀,你看到上面师傅与鹰妹讨论那首歌词了吧 -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (22 bytes) () 04/18/2010 postreply 01:18:02

老熊对鹰姐姐的爱 -hahaman- 给 hahaman 发送悄悄话 hahaman 的博客首页 (8 bytes) () 04/18/2010 postreply 08:01:38

haha,我倒是觉得:你再多嘴,熊老会跟你发熊疯的。 -戏雨飞鹰- 给 戏雨飞鹰 发送悄悄话 戏雨飞鹰 的博客首页 (0 bytes) () 04/18/2010 postreply 09:48:10

sweetie 哈哈慢的很多话都令我失望 -bearsback- 给 bearsback 发送悄悄话 bearsback 的博客首页 (26 bytes) () 04/18/2010 postreply 10:51:08

密碼厲害! -Carpediem- 给 Carpediem 发送悄悄话 Carpediem 的博客首页 (111 bytes) () 04/17/2010 postreply 23:02:18

密码有才有闲也不怕揍,厉害~ -lilac09- 给 lilac09 发送悄悄话 lilac09 的博客首页 (1131 bytes) () 04/18/2010 postreply 08:03:26

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